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 Modern Techniques for Polymer Characterisation

 

Modern Techniques for Polymer Characterisation

Concerned primarily with the determination of the size of polymer molecules in solution, their sequence structure and also molecular weight characteristics, this book includes contributions relating to molecular weight and molecular weight characteristics using conventional chromatographic techniques, spectroscopic techniques describing determination of sequence structure, and scattering techniques concerned with the determination of macromolecular size.

The book will be invaluable for postgraduate and research polymer chemists and all those who are concerned with the study and use of macromolecular materials. The techniques described reflect some of the most recent advances which have been made in the development of methods for molar mass characterisation and also the size of molecules in solution and solid phases. The problem of molar mass characterisation is common to synthetic and biological polymers, hence this book will also be of interest to biologists, polymer engineers and technologists. Techniques covered include: Temperature Rising Elution Fractionation Field Flow Fractionation Static and Dynamic Light Scattering Neutron Scattering Vapour Pressure Osmometry/Viscometry Ultrafugation and Sedimentation Gel Electrophoresis of Biological Macromolecules Mass Spectrometry of Polymers

 

 Proton and Carbon NMR Spectra of Polymers, 5th Edition

 

Proton and Carbon NMR Spectra of Polymers, 5th Edition

The fifth edition of this outstanding reference work contains a much expanded range of NMR spectra, and includes a full CD-ROM version.

The material included in this work provides information on polymer microstructure or fine structure, which results from normal and abnormal addition modes, arising from secondary reactions, as well as tacticity or stereochemical arrangement of monomer units in the main chain of the skeleton.

Covering 1H and 13C NMR spectra of soluble (1H and 13C) and swollen gelled (13C) synthetic polymers, appropriate NMR analytical conditions are specified and all resonances, often obtained at different frequencies, are interpreted, together with details concerning the homopolymer (tacticity, molecular weight, chain lengths, etc) or copolymer (composition, distribution of comonomer units, etc) skeletons.

The polymer spectra are grouped in families: acrylics; amides; dienes; esters; ethers; olefins; siloxanes; styrenes and their derivatives; urethanes; vinyls; vinylidenes

   

Compositional and Failure Analysis of Polymers: A Practical Approach

 

Compositional and Failure Analysis of Polymers: A Practical Approach

Intended as a practical guide for polymer technologists, engineers and analysts in the plastics, composites and rubber fields, this title describes a range of techniques and strategies for compositional and failure analysis of polymeric materials and products. Numerous examples illustrate the application of analytical methods for solving commonly encountered problems in the polymer industry. The reader is guided towards the most appropriate method of analysis and measurement and the most likely reasons for the failure.

Areas covered include:

  • Migration and interaction of additives
  • Mechanical stress and stress cracking
  • Crazing and fracture
  • Residual stress and weld lines
  • Contamination and discoloration

Numerous pedagogical methods, illustrative flow diagrams, figures and tables are used throughout the text to make it an invaluable guide to all analysts and polymer engineers in industrial or academic laboratories

 

Preparative Methods of Polymer Chemistry, 3rd Edition

 

Preparative Methods of Polymer Chemistry, 3rd Edition

The long-awaited Third Edition of the classic in polymer synthesis

Thirty years ago, the Second Edition of Preparative Methods of Polymer Chemistry further established its reputation as the laboratory bible for polymer synthesis. The last three decades have witnessed a deeper understanding of the principles involved in preparing and processing polymers, leading to tremendous advances in polymer synthesis. Guiding practicing scientists through the methods of synthesizing polymers, the Third Edition retains theory and vital protocols, while revising and updating the sections on synthesis, fabrication techniques, and characterization methods.

Delving into the physical and chemical aspects of polymer processing, each chapter includes a discussion of the relevant background and principles, enabling the scientist to apply synthetic techniques intelligently. The Third Edition also contains sections on current topics such as:

  • Extended-chain polymer technology
  • High-temperature and high-performance polymers
  • Carbon fibers
  • Electrically conductive polymers
  • Group-transfer polymerization
  • Composites

Preparative Methods of Polymer Chemistry, Third Edition provides essential information for both students and practicing polymer scientists.

   

Atlas of Polymer and Plastics Analysis/Atlas der Polymer- und Kunststoffanalyse, Volume 1, Defined Polymers/ Band 1: Definierte Polymere

Atlas of Polymer and Plastics Analysis/Atlas der Polymer- und Kunststoffanalyse, Volume 1, Defined Polymers/ Band 1: Definierte Polymere
Atlas of Polymer and Plastics Analysis: Volume 3: Additives and Processing Aids

 

 Modern Polymer Spectroscopy

 
Modern Polymer Spectroscopy
Modern Polymer Spectroscopy Edited by Giuseppe Zerbi Modern Polymer Spectroscopy provides a ‘guided tour’ to the state of the art in polymer analysis by vibrational spectroscopy. Five renowned experts describe new experimental and theoretical techniques of current interest to both university and industrial laboratories. Areas of focus include:
  • two-dimensional infrared spectroscopy
  • segmental mobility of liquid crystalline polymers under external fields
  • dynamics and structure of polymers with chemical and structural disorder
  • spectra of polyconjugated conducting polymers
  • theoretical calculations on biopolymers.

Readers learn experimental techniques or theoretical tools essential for obtaining more valuable information from their vibrational spectra that can be used for solving a variety of sophisticated problems in both basic and applied science. Some of these problems cannot be solved with other techniques. An essential reference for all professionals who need to keep abreast with the latest developments in the field, graduate students in polymer science, material science and the biosciences using spectroscopic techniques will profit from the wealth of information provided in this novel, state-of-the-art guide.

 

Molecular Modeling of Polymers

 

Molecular Modeling of Polymers

Stereochemical Structure-Property Relationships in Polynorbornene From Simulation (S. Ahmed, et al.).

Determination of the Polymer Tacticity From Calculation of Infrared Spectra Based on Classical Molecular Simulations (A. Soldera).

Comparison Between the Glass Transition Temperatures of the Two PMMA Tacticities: A Molecular Dynamics Simulation Point of View ( A. Soldera).

Local Dynamics and Glass Transition (B. Erman & I. Bahar).

Dynamics of Bulk Polyethylene on a High Coordination Lattice (P. Doruker & W. Mattice).

Simulation Study of Semi-Crystalline Polymer Interphases (S. Balijepalli & G. Rutledge).

Micro/Mesoscopic Approaches to the Ring Formation in Linear Wormlike Micellar Systems (M. Kröger).

 

Polymer Spectroscopy

Polymer Spectroscopy


 

 

 New Characterization Techniques for Thin Polymer Films

New Characterization Techniques for Thin Polymer Films
Various industries and universities have aimed their activities toward the development of highly sensitive techniques capable of studying ultrathin polymer films. Provides researchers with a working description of the principles of operation, areas of application and data analysis methods for some of the newly developed techniques, as well as sufficient references for future in-depth studies of thin polymer films. The techniques covered are divided into two groups--bulk property measurements and surface/interface property measurements--with chapters covering microdielectrometry, stress measurement by x-ray diffraction, laser interferometry, ion beam analysis, photothermal analysis, and XPS/SIMS/AES, among other techniques. Abstracts for each of the chapters are conveniently located in the preface.
 

Polymer Characterization: 7th International Conferences on Polymer Characterization (POLYCHAR 7)

Polymer Characterization: 7th International Conferences on Polymer Characterization (POLYCHAR 7)

Advances in Scanning Probe Microscopy of Polymers

Advances in Scanning Probe Microscopy of Polymers

The symposium "Recent Advances in Scanning Probe Microscopy of Polymers" held during the 220th American Chemical Society National Meeting in Washington DC in August 2000 focused on the latest advances in applications of SPM techniques for the study of polymeric and organic materials. The main topics consisted of SPM imaging of polymer morphology and microstructure, microtribological properties of polymers, micromechanical probing of polymers, microthermal imaging, studies of ultrathin and molecular organic and polymeric films, modeling of tip-surface interactions, chemical compositional analysis of heterogeneous materials, and SPM applications to industrial polymers.
This volume of Macromolecular Symposia will be a valuable guide in the field of contemporary SPM studies of polymeric materials.

Polymer Characterization and Materials Science

Polymer Characterization and Materials Science

The UNESCO School and IUPAC Conference in April 2001 was the fourth to be held in Stellenbosch, South Africa. World authorities are invited to give tutorials at the School and presentations at the Conference to expose South African students and researchers to new ideas in the area of macromolecular science. Continuing the theme of Macromolecules and Materials Science, the focus was on polymer characterization, new polymer architectures and nanomaterials. A number of papers presented at the Conference are collected in this volume of Macromolecular Symposia.

Polymer Processing and Structure Relationships: EUROMAT 2001, Rimini, Italy, June 10-14 2001

Polymer Processing and Structure Relationships: EUROMAT 2001, Rimini, Italy, June 10-14 2001

The rapid development of polymer technology in recent years has produced an increasing range of new polymers and additives, and seen much innovation in processing technologies. The need for understanding the relationships between polymeric structure, processing conditions and material properties is therefore greater than ever before. The EUROMAT 2001 conference held in June 2001 in Rimini, Italy was an ideal international forum for dealing with this complex subject. Selected lectures are presented in this volume of Macromolecular Symposia, which should be of interest to scientists of polymer chemistry and of polymer blending, processing and recycling, in academia and industry, alike.

Polymer Spectroscopy: 14th European Symposium on Polymer Spectroscopy (ESOPS 14)

 

Polymer Spectroscopy: 14th European Symposium on Polymer Spectroscopy (ESOPS 14)

Spectroscopic techniques are among the most developed and useful tools for investigating bulk polymers and polymer surfaces. The variety of sepectroscopic analyses possible is very broad, and includes IR, Raman, UV/vis, fluorescence, NMR, EPR, mass spectroscopy, XPS, EELS, electrical, mechanical and ultrasound. These methods can be used to study characteristics such as order and crystallinity, phase transitions, deformation and viscoelasticity, and also surface modification. All these topics as well as modern trends such as the application of electric fields and supercritical fluids, and in-line process monitoring, were discussed at the 14th European Symposium on Polymer Spectroscopy (ESOPS 14) held in Dresden, Germany in September 2001, and are presented in this volume of macromolecular Symposia

Scattering Methods for the Investigation of Polymers: 20th Discussion conference, Prague July 9-12, 2001

 

Scattering Methods for the Investigation of Polymers: 20th Discussion conference, Prague July 9-12, 2001

Scattering methods as important tools for the characterization of the structure and dynamics of polymers provided the theme for the 60th meeting in the series of the Prague Meetings on Macromolecules held in July, 2001. Highlights included discussion of the following topics:
  • Light, X-ray, and neutron scattering techniques
  • Applications of these methods to a variety of polymeric materials and systems

Papers based on the main lectures, special lectures, and panel discussions presenting recent research on these topics have been collected and are available in this volume of Macromolecular Symposia.

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 Polymer Analysis Amazon Price: £71.80

This book introduces the techniques used for the analysis of polymers. It covers the main aspects of polymer science and technology; identification, polymerization, molecular weight, structure, surface properties, degradation and mechanical properties.   Clear explanations of each analytical technique.  Describes the application of techniques to the study of polymers.  Encourages learning through numerous self-assessment questions and answers. Structured for flexible learning

Table of Contents
Introduction

Identification

Polymerization

Molecular Weight

Structure

Surface Properties

Degradation

 

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Thermal Analysis: Fundamentals and Applications to Polymer Science Amazon Price: £70.00
 

Book Description
This new edition of a well-received work discusses the role of thermal analysis (TA) in the development of new polymeric materials with specific thermal related characteristics such as the ability to withstand extreme weather conditions and temperatures. Focusing on the principles and applications of thermal analysis in the polymer industry, this edition complements Dr. Hatakeyama's new work, Handbook of Thermal Analysis, which offers practical technical information and data tables.

Synopsis
This handbook has been designed to acquaint newcomers to the field of thermal analysis (TA) by providing a detailed introduction to the basic principles of instrument operation, advice on sample preparation and a guide to the interpretation of results. The text can be followed in the course of routine lab work. The main TA techniques considered include differential scanning calorimetry, differential thermal analysis and thermogravity.

Table of Contents

Thermal Analysis.
Differential Thermal Analysis and Differential Scanning Calorimetry.
Calibration and Sample Preparation.
Thermogravimetry.
Applications of Thermal Analysis.
Other Thermal Analysis Methods.
Appendices.
Indexes.

     Attenuated Total Reflectance...

Combining theoretical fundamentals with practical applications of attenuated total reflectance to the analysis of polymers and polymeric materials, this text provides a quantitative approach to the analysis and interpretation of attenuated total reflectance. It discusses sampling and microsampling techniques suitable for use with attenuated total reflectance analyses and examines the advantages and disadvantages of attenuated total reflectance spectroscopy

     Photon, Electron, and Ion Probes of... Amazon Price: £45.00

 

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 Atlas of Polymer and Plastics Analysis: Defined Polymers   Amazon Price: £285.00

Intended for polymer chemists, plastics technologists, analytical chemists, spectroscopists and those working in plastics industries and analytical laboratories, this is the first volume of the third edition of an atlas of polymer and plastics analysis. The work has been enlarged and completely revised and contains almost 3200 FT-IR-spectra on polymers newly developed since 1980, together with information on source, preparation, structural and molecular formulae, decimal numbers and bibliography. All spectra have been measured on either modern computer-aided dispersive spectrometers or the FT-IR method, and the key to each spectra gives information on source synthesis and preparation of the polymer.

 

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 Mass Spectrometry of Polymers  Amazon Price: £107.00

Mass spectrometry of polymers illustrates how modern mass spectrometry can be an indispensable tool for polymer characterization. Detailing the most current applications of MS to synthetic polymers, revamping today's well-established protocols

 

 

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   Polymer Surface Modification and Characterization    

The book is written clearly by someone who has an excellent grasp of the modification methods and characterisation tools. The book is packed full of useful information whilst remaining compact and succinct. Unusually, the author has managed to combine a high scientific level with commercial aspects such as cost. For example, he compares the relative merits of corona treatment versus flame treatment and plamsa treatment of polymers. There is also an excellent chapter on surface energy measurement and some warnings about complications when making contact angle measurements

     Polymer Analysis and Degradation Amazon Price: £70.50

Scientists from many countries explore the elementary reactions in polymer matrix with an eye to slowing degradation of the material and so increasing the life span of polymer products in use or storage. They discuss such aspects as the interaction between polymers and the nitrogen oxides in pollute

     Atlas of Polymer and Plastics Analysis: Defined Polymers   Amazon Price: £235.00

Intended for polymer chemists, plastics technologists, analytical chemists, spectroscopists and those working in plastics industries and analytical laboratories, this is the first volume of the third edition of an atlas of polymer and plastics analysis. The work has been enlarged and completely revised and contains almost 3200 FT-IR-spectra on polymers newly developed since 1980, together with information on source, preparation, structural and molecular formulae, decimal numbers and bibliography. All spectra have been measured on either modern computer-aided dispersive spectrometers or the FT-IR method, and the key to each spectra gives information on source synthesis and preparation of the polymer.

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Methods of X-ray and Neutron Scattering in Polymer Science (Topics in Polymer Science)  Amazon Price: £55.00

Book Description
This book presents the basic theories underlying x-ray and neutron scattering, as well as the various techniques that have been developed for their application to the study of polymers. The two scattering methods are discussed together from the beginning, so as to allow readers to gain a unified view of the scattering phenomena. The book is introductory and may be used as a textbook in polumer science class or for self-study by polymer scientists new in scattering techniques.

Synopsis
Presents the basic theories underlying X-ray and neutron scattering, as well as the various techniques that have been developed for their application to the study of polymers. The two scattering methods are discussed together from the beginning, so as to allow readers to gain a unified view of the scattering phenomena. The book is introductory and may be used as a textbook in polymer science class or for self-study by polymer scientists new in scattering techniques.

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Modern Polymer Spectroscopy Amazon Price: £100.00

Book Description
International experts present state-of-the art information on vibrational spectroscopy--covering both the theoretical and practical aspects of this field.

Synopsis
This text on polymer spectroscopy includes chapters on: two-dimensional infrared spectroscopy; segmental mobility of liquid crystals and liquid-crystalline polymers under external fields; and vibrational spectra as a probe of structural order/disorder in chain molecules and polymers.

Table of Contents

Two-Dimensional Infrared Spectroscopy.
Segmental Mobility of Liquid Crystals and Liquid-Crystalline Polymers under External Fields.
Vibrational Spectra as a Probe of Structural Order/Disorder in Chain Molecules and Polymers.
Vibrational Spectroscopy of Intact and Doped Conjugated Polymers and their Models.
Vibrational Spectroscopy of Polypeptides.

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NMR Spectroscopy & Polymer Microstructre Amazon Price: £97.95

Book Description
The various techniques used to analyze the microstructures of polymers are presented in this book. High resolution and solid state techniques are described, and applications to both synthetic and biological polymers are discussed in detail.

Particular emphasis is placed on the determination of polymer microstructure by NMR spectroscopy. Here attention is drawn to the connection between the microstructures and NMR spectra of polymers, and it is demonstrated that the local polymer conformation provides this link. The numerous examples illustrating this connection are a special feature of the book

Table of Contents

Preface

1. The Microstructure of Polymer Chains

1.1 Introduction

1.2 Polymers Are Macromolecules

1.3 Polymer Microstructures from Polymerization of Monomers

1.4 Organization of Polymer Chains

1.5 Polymer Properties and Their Relation to Microstructure

2. Nuclear Magnetic Resonance

2.1 Introduction

2.2 The NMR Phenomenon

2.3 Experimental Observation of NMR

3. High-Resolution NMR of Polymers

3.1 Introduction

3.2 1H NMR

3.4 High-Resolution 13C NMR in the Solid State

3.5 Two-Dimensional NMR

3.6 Other Nuclei--15N, 19F, 29Si, and 31p

4. 13C NMR of Polymers

4.1 Introduction

4.2.4 γ-gauche Effects in 13C NMR

5. γ-gauche Effect Method of Predicting 13C NMR Chemical Shifts

5.1 Introduction

5.2 Polymer Conformations

5.3 γ-gauche Effect Calculation of 13C NMR Chemical Shifts

6. Determination of Stereosequences in Vinyl Polymers

6.1 Introduction

6.2 Traditional Methods

6.4 Application of γ-gauche Effect Method

6.5 Establishing Vinyl Polymerization Mechanisms from Stereosequence Analysis

7. Microstructural Defects in Polymers

7.1 Introduction

7.2 Determining the Regiosequence of PVF2

8. Copolymer Microstructure

8.1 Introduction

8.2 Comonomer Sequences

8.3 Copolymer Stereosequences

8.4 Copolymer Conformations

8.5 Copolymerization Mechanisms

9. Chemically Modified Polymers

9.1 Introduction

9.2 Transformation of PVC to Ethylene-Vinyl Chloride Copolymers

9.3 Modification of 1,4-Poly(butadienes) with Dihalocarbenes

10. Biopolymers

10.1 Introduction

10.2 Polypeptides

10.3 Polynucleotides

10.4 Polysaccharides

11. Solid Polymers

11.1 Introduction

11.2 Solid-State Polymer Conformation

11.3 Interchain Packing in Solid Polymers

11.4 Molecular Motion in Solid Polymers

11.5 Application of CPMAS/DD 13C NMR to Solid Polymers

11.6 Other Nuclei Observed In Solid-State Polymer Spectra

11.7 Concluding Remarks

 

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Molecular Weight Determination (Wiley Series in Chemical Analysis)

AmazonPrice: £206.00

Book Description
Presents the state-of-the-art in molecular weight distribution of polymeric materials. First chapter covers the concepts of molecular averages and distribution functions for polydisperse polymer systems. Chapters 2 through 4 summarize techniques for determining number average molecular weight. Following chapters cover all the modern techniques for determining molecular weight, including classical light scattering, x-ray scattering, neutron scattering, use of the ultracentrifuge, viscometric determination, viscoelastic measurements, fractionation techniques, chromatographic techniques, mass spectrometry, as well as methods for characterizing insoluble polymers. Final chapter surveys the various types of standard polymers available for commercial sources.

Synopsis
Presented here is the state-of-the-art in molecular weight distribution of polymeric materials. The first chapter covers the concepts of molecular averages and distribution functions for polydisperse polymer systems. Chapters 2 through 4 summarize techniques for determining number average molecular weight. Following chapters cover all the modern techniques for determining molecular weight, including classical light scattering, X-ray scattering, neutron scattering, use of the ultracentrifuge, viscometric determination, viscoelastic measurements, fractionation techniques, chromatographic techniques, mass spectrometry, as well as methods to characterize insoluble polymers. The final chapter surveys the various types of standard polymers available for commercial sources. The volume has been designed specifically for chemical engineers and polymer scientists.

 

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Polymers: Polymer Characterization and Analysis (Encyclopaedia Reprint Series)  Amazon Price: £174.00
 

Book Description
This volume is one of a series of selected reprints from the world-renowned Encyclopedia of Polymer Science and Engineering designed to provide specific audiences with articles grouped by a central theme. Included are all of the original articles related to polymer characterization and analysis, with full texts, tables, figures, and reference materials from the original--reproduced unchanged. Articles are by industrial or academic experts in their field. Includes coverage of the newest analytical methods, a wealth of physical and mechanical data, and standards and specifications for materials. Alphabetical organization, extensive cross-references, and a complete index further enhance its usefulness.

Synopsis
This volume is one of a series of selected reprints from the "Encyclopedia of Polymer Science and Engineering", designed to provide specific audiences with articles grouped by a central theme. Included are all of the original articles related to polymer characterization and analysis, with full texts, tables, figures and reference materials from the original reproduced unchanged. Articles are by industrial or academic experts in their field. The text includes coverage of the newest methods, a wealth of physical and mechanical data and standards and specifications for materials. Alphabetical organization, extensive cross-references, and a complete index further enhance the usefulness of this volume.

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The Vibrational Spectroscopy of Polymers... Amazon Price: £22.95

Synopsis
This book describes the theory and practice of infrared and Raman spectroscopy as applied to the study of the physical and chemical characteristics of polymers. Its purpose is to give the beginning researcher in the field a firm foundation and a starting point for the study of more-advanced literature. To this end the book concentrates on the fundamentals of the theory and nomenclature, and on the discussion of well-documented illustrations of these fundamental principles, including many now-classic studies in the subject. No previous knowledge of either polymers or vibrational spectroscopy is assumed. The book will be of value to anyone beginning research on the vibrational spectroscopy of polymers, either from a physics or a chemistry background. It is intended to be especially suitable for use in undergraduate courses in physics, chemistry or materials science at both universities and polytechnics

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Modern Methods of Polymer Characterization Amazon Price: £145.00

Book Description
Presents the methods used for characterization of polymers. In addition to theory and basic principles, the instrumentation and apparatus necessary for methods used to study the kinetic and thermodynamic interactions of a polymer with its environment are covered in detail. Some of the methods examined include polymer separations and characterization by size exclusion and high performance chromatography, inverse gas chromatography, osmometry, viscometry, ultracentrifugation, light scattering and spectroscopy.

Synopsis
A practical reference offering detailed descriptions of methods used to study the kinetic and thermodynamic interactions of a polymer within its environment. Each chapter addresses the theory, basic principles, instrumentation and apparatus of the polymer characterization method